The crystal structure of N-((3,5-di-tert-butyl-4-hydroxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide, C28H35N3S

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2,6-Di-tert-butyl-4-[(N-methyl­anilino)meth­yl]phenol

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The title compound, C(20)H(32)N(2)O(2)S, the condensation product of a thio-acetohydrazine and acetone, has a two-coordinate S atom and the angle at this atom is 100.7 (1)°. The (CH(3))C=N-NH-C(O)- substituent engages in N-H⋯O hydrogen-bonding inter-actions with the substituent of an adjacent mol-ecule across a center of inversion, generating a dimeric structure.

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2,6-Di-tert-butyl-4-(methoxy­meth­yl)phenol

The title compound, C(16)H(26)O(2), was easily obtained in high yield when 4-bromo-methyl-2,6-di-tert-butyl-phenol was reacted with methanol. There are two independent mol-ecules in the asymmetric unit. The meth-oxy group in each of the independent mol-ecules was found to be disordered, with site-occupation factors of 0.8728 (18)/0.1272 (18) and 0.8781 (17)/0.1219 (17).

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The title compound, C(17)H(29)NO, is an important hindered phenol derivative. The asymmetric unit contains two mol-ecules. Molecules inter-act through O-H⋯N hydrogen bonds to form a tetramer arranged around a twofold rotation axis.

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Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol

The essential part (including all the non-hydrogen atoms except two methyl carbons) of the mol-ecule of the title compound, C21H26N4O5, lies on a mirror plane, which bis-ects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intra-molecular N-H⋯O hydrogen bond present, forming an S(6) ring motif. In the crystal, mol-ecules are linked via O-H...

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ژورنال

عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures

سال: 2018

ISSN: 2197-4578,1433-7266

DOI: 10.1515/ncrs-2017-0257